AIRGAS -- NITROGEN, COMPRESSED GAS (UN1066) -- 6830-01-106-0895
===================== Product Identification ===================== Product ID:NITROGEN, COMPRESSED GAS (UN1066) MSDS Date:10/02/1995 FSC:6830 NIIN:01-106-0895 === Responsible Party === Company Name:AIRGAS Address:100 MATSONFORD RD City:RADNOR State:PA ZIP:19087-4579 Country:US Info Phone Num:610-687-5253 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:AIRGA === Contractor Identification === Company Name:AIRGAS Address:100 MATSONFORD ROAD, 5 RADNOR CORP CNTR City:RADNOR State:PA ZIP:19087 Country:US Phone:215-687-5253 CAGE:AIRGA Company Name:AIRGAS INC Address:100 MATSONFORD RD SUITE 550 Box:City:WAYNE State:PA ZIP:19087 Country:US Phone:215-687-5253 CAGE:0MN39 ============= Composition/Information on Ingredients ============= Ingred Name:NITROGEN CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: >99% OSHA PEL:N/K ACGIH TLV:ASPHYXIANT Ingred Name:INERT INGREDIENTS; (OTHER INERTS) Fraction by Wt: <1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:OXYGEN CAS:7782-44-7 RTECS #:RS2060000 Fraction by Wt: <0.1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:MATL TO AVOID: MAY BE EXPLOSIVE. TITANIUM: WILL BURN IN NITROGEN ATMOSPHERE. RTECS #:9999999ZZ Ingred Name:RESP PROT: EXCEED WORKING LIMS OF RESP & BE NIOSH/MSHA APPRVD. ANY SUPPLIED-AIR RESP OPERATED IN PRESS-DEMAND OR (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: OTHER POSITIVE PRESS MODE. ANY SELF-CONTAINED BREATHING APPARATUS. RTECS #:9999999ZZ Ingred Name:EFTS OF OVEREXP: FROSTBITE W/REDNESS, PAIN & BLURRED VISION. INGEST OF GAS IS UNLIKELY. INGEST: IF LIQ IS (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: SWALLOWED, FROSTBITE DAMAGE OF LIPS, MOUTH & MUCOUS MEMBRANES MAY OCCUR. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: TO USE, GENTLY WRAP AFFECTED PART IN BLANKETS. ENCOURAGE VICTIM TO EXERCISE AFFECTED PART WHILE (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9:IT IS BEING WARMED. ALLOW CIRCULATION TO RETURN NATURALLY. GET MED ATTN IMMED. EYES: IMMED WASH EYES W/LG (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: AMTS OF WATER, OCCAS LIFTING UPPER & LOWER LIDS UNTIL NO EVID OF IRRIT REMAINS (AT LEAST 15-20 MIN). IF (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: FROSTBITE IS PRESENT, WARM WATER MAY BE PREF. GET MED ATTN IMMED. ANTIDOTE: NO SPECIFIC ANTIDOTE. TREAT (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: SYMPTOMATICALLY & SUPPORTIVELY. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHAL: SEE INFO OF SIMPLE ASPHYS. NITROGEN INHALED UNDER INCRD ATMOSPHERIC PRESS (>1.5 ATMS), MAY DISSOLVE IN FAT-CONTAINING BRAIN CELLS & ACT AS ANESTH, CAUSING NARCOSIS. PERSONS WHO HAVE BEEN EXPOS TO INCRD PRESS FOR A TIME & WHO ARE SUDDENLY RELSD FROM PRESS MAY DEVELOP DECOMPRESSION SICKNESS. SKIN (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: CNTCT: NO ADVERSE EFTS HAVE BEEN REPORTED FROM GAS. DUE TO RAPID EVAP, LIQ MAY CAUSE FROSTBITE W/REDNESS, TINGLING & PAIN OR NUMB. IN MORE SEV CASES, SKIN MAY BECOME HARD & WHITE & DEVELOP B LISTERS. EYE: GASEOUS NITROGEN MAY CAUSE IRRIT IF SPRAYED DIRECTLY INTO EYES. DUE TO RAPID EVAP LIQ MAY CAUSE (ING 7) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST: GET MED ATTN IMMED . IF ADVERSE EFTS OCCUR, TREAT SYMPTOMATICALLY & SUPPORTIVELY & GET MED ATTN. INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE OXYGEN/ARTF RESP) . SKIN: IT IS UNL IKELY THAT EMER TREATMENT WILL BE REQD.IF ADVERSE EFTS OCCUR, GET MED ATTN. IN CASE OF FROSTBITE, WARM AFFECTED SKIN IN WARM WATER AT TEMP OF 107F. IF WARM WATER IS NOT AVAIL/IMPRACTICAL (ING 9) ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR HALON. FOR LARGER FIRES, USE WATER SPRAY, FOG OR STANDARD FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. MOVE CNTNR FROM FIRE AREA IF POSS. STAY AWAY FROM STORAGE TANK ENDS. COOL FIRE-EXPOS CNTNRS W/WATER (SUPDAT) Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:STOP LEAK IF YOU CAN DO IT WITHOUT RISK. KEEP UNNECESSARY PEOPLE AWAY; ISOLATE HAZARD AREA AND DENY ENTRY. VENTILATE CLOSED SPACES BEFORE ENTERING. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN ACCORDANCE WITH 29 CFR 1910.101. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. Other Precautions:DO NOT PERMIT PHYSICAL DAMAGE OR OVERHEATING OF CONTAINERS. CONTENTS ARE UNDER PRESSURE; CONTAINERS MAY VIOLENTLY RUPTURE AND TRAVEL A CONSIDERABLE DISTANCE. CONTACT LENSES SHOULD NOT BE WORN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:THE FOLLOWING RESPS ARE RECOM BASED ON INFO FOUND IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN ORDER FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE BASED ON CONTAM LEVELS FOUND IN WORK PLACE, MUST NOT (ING 5) Ventilation:PROVIDE GENERAL DILUTION VENTILATION. Protective Gloves:WEAR FULL PROT, COLD INSULATING GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health FIRE FIGHT PROC: FROM SIDE UNTIL WELL AFTER FIRE IS OUT. WITHDRAW IMMED IF RISING SOUND FROM VENTING SFTY DEVICE OR ANY DISCOLORATION OF STORAGE TANKS DUE TO FIRE. EXTING USING AGENT SUITABLE FOR TYPE OF SURROUNDING FIRE. COOL CNTNRS W/FLOODING QTYS OF WATER FROM AS FAR A DISTANCE AS POSSIBLE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-321F,-196C Melt/Freeze Pt:M.P/F.P Text:-346F,-210C Vapor Pres:760 @-196C Vapor Density:1.2506 @0C Spec Gravity:0.967 Solubility in Water:1.485 VOL/VOL @ 25C Appearance and Odor:ODORLESS, TASTELESS, COLORLESS, INERT GAS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES LITHIUM: MAY IGNITE IN GAS. MAGNESIUM: VIOLENT RXN W/LIQ ON IGNIT. NEODYMIUM: VIGOROUS RXN. OZONE: MIXS OF GASES (ING 4) Stability Condition to Avoid:DO NOT PERMIT PHYSICAL DAMAGE OR OVERHEATING OF CONTAINERS. Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF NITROGEN. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FED, STATE & LOC REGS WHEN STORING/DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE CONTACT DISTRICT DIRECTOR OF EPA. VENT NITROGEN GAS SLOWLY TO WELL-VENTD OUTDOOR LOCATION REMOTE FROM PERS WO RK AREAS & BLDG AIR INTAKES. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.